Anish Mistry, Ben Moreton, et al.
Chemistry - A European Journal
Turning a new leaf: The first structures isolated from Thuiaria breitfussi, the breitfussins, are presented. This structural class consists of indole-oxazole-pyrrole units. Limited quantities prevented crystallization; therefore, the structures were solved using a novel combination of AFM, computer-aided structure elucidation (CASE), and DFT calculations. Visualization by AFM determined all the connection points of the cyclic systems and the other substituents. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.