Application of the hypernetted chain approximation to the electric double layer at a charged planar interface

Douglas Henderson; Lesser Blum; William R. Smith

doi:10.1016/0009-2614(79)87041-4

Chemical Physics Letters

Paper

15 May 1979

Application of the hypernetted chain approximation to the electric double layer at a charged planar interface

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Abstract

The hypernetted chain approximation is used to calculate the density and charge profiles and the potential difference of a fluid of charged hard spheres near a charged planar wall. The charge profile is not monotonic. © 1979.

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Abstract

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Some simple calculations of the density profile of inhomogeneous hard spheres using the Lovett-Mou-Buff-Wertheim equation with the bulk direct correlation function

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