Reinhard Schinke, William A. Lester Jr.
The Journal of Chemical Physics
A quantum mechanical scattering study is carried out to test a collisional pumping model for cooling the 6 and 2 cm doublets of interstellar formaldehyde. The Arthurs and Dalgarno formalism is extended to the collision of an s-state atom with a rigid asymmetric top molecule and applied to rotational excitation of ortho formaldehyde by helium impact. Using a previously determined configuration interaction potential energy surface, the coupled-channel (CC) equations are integrated at 12 scattering energies between 20 and 95°K. Up to 16 ortho formaldehyde states, yielding a maximum of 62 CC equations, are retained to test convergence of computed cross sections. Resonance structure is obtained at ∼20.2, 32.7, and 47.7°K. The computed inelastic cross sections are averaged over a Maxwell-Boltzmann distribution and the resultant rates used to solve the equations of statistical equilibrium for the relative populations. The 6 and 2 cm doublets are found to be cooled only upon inclusion of the j = 3 doublet. Copyright © 1976 American Institute of Physics.
Reinhard Schinke, William A. Lester Jr.
The Journal of Chemical Physics
Joachim Schaefer, William A. Lester Jr., et al.
Chemical Physics Letters
Sheldon Green, Barbara J. Garrison, et al.
The Journal of Chemical Physics
Andrew W. Raczkowski, William A. Lester Jr., et al.
The Journal of Chemical Physics