Electronic control of the stereoselectivities of electrocyclic reactions of cyclobutenes against incredible steric odds

K.N. Houk; David C. Spellmeyer; Charles W. Jefford; C.G. Rimbault; Ying Wang; R.D. Miller

doi:10.1021/jo00244a058

Journal of Organic Chemistry

Paper

01 May 2002

Electronic control of the stereoselectivities of electrocyclic reactions of cyclobutenes against incredible steric odds

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Abstract

Experimental studies of the electrocyclic reactions of 2- and 3-tert-butyl-3-(trimethylsiloxy)cyclobutene and of 3-methoxy-3-fert-butylcyclobutene confirm ab initio computational predictions. © 1988, American Chemical Society. All rights reserved.

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