Eliminative deoxygenation: A facile synthesis of α-cyano and α-carboalkoxy substituted vinyl sulfides

R.D. Miller; R. Hässig

doi:10.1016/S0040-4039(00)94836-6

Tetrahedron Letters

Paper

01 Jan 1985

Eliminative deoxygenation: A facile synthesis of α-cyano and α-carboalkoxy substituted vinyl sulfides

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Abstract

The faciIe eliminative deoxygenation of α-cyano and carboalkoxy sulfoxides by trimethylsilyl triflate under mildly basic conditions results in the formation of α-thiophenyl substituted α,β-unsaturated nitriles and esters in high yields. © 1985.

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