Brian D. Gilbert, Charles S. Parmenter, et al.
The Journal of Chemical Physics
Rotationally and vibrationally inelastic scattering from the level v′ = 35 with J′ = 8-11 in the B Ou+ electronic state of I2 have been followed in a crossed molecular beams experiment using H2 and D2 target gases. Center-of-mass collision energies are 89 and 103 meV, respectively. I2 B Ou+ is excited by a laser pump and the inelastic scattering is followed by dispersed B → X fluorescence. The signal-to-noise is good enough to obtain relative cross sections for I2 scattering for Δv′'s extending to ±7. The cross sections are remarkably symmetric with respect to gain vs loss of vibrational quanta. They decrease exponentially with increasing |Δv′| for each target, but H2 has a steeper decline. Collision momentum rather than velocity differences appears to be responsible for this isotope effect. The mean vibrational energy change per state-changing collision is only about -9 cm-1 for both H2 and D2, a small fraction of the 60-cm-1 vibrational quantum size. Rotationally inelastic scattering produces 2-3 times more rotational excitation with the heavier isotope D2, a consequence of angular momentum conservation. © 1988 American Chemical Society.
Brian D. Gilbert, Charles S. Parmenter, et al.
The Journal of Chemical Physics
Douglas J. Krajnovich, Kirk W. Butz, et al.
The Journal of Chemical Physics
Kirk W. Butz, Jeffrey R. Johnson, et al.
The Journal of Chemical Physics
Douglas J. Krajnovich, Kirk W. Butz, et al.
The Journal of Chemical Physics