Pair correlation of hard spheres near a hard wall
Michael Plischke, Douglas Henderson
Journal of Physical Chemistry
The modified Gouy-Chapman theory of the electrical double layer in which ion-core effects among the ions are neglected, but are taken into account in the ion-electrode interaction, is applied to the case of 1:1, 2:2, 1:2, and 2:1 electrolytes for both equal and unequal ionic diameters. At large charge densities on the electrode, the counterions dominate and the results approach those of a symmetric electrolyte. However, at small charge densities on the electrode, the effects of asymmetry are evident. In particular, for unequal ionic diameters, a nonzero potential can occur at zero charge on the electrode, even in the absence of specific adsorption. © 1983 American Institute of Physics.
Michael Plischke, Douglas Henderson
Journal of Physical Chemistry
Peter J. Leonard, Douglas Henderson
Molecular Physics
Douglas Henderson, John A. Barker, et al.
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
Lesser Blum, Douglas Henderson, et al.
Journal of Electroanalytical Chemistry