Shiyi Chen, Daniel Martínez, et al.
Physics of Fluids
This article describes studies on the catalytic activity of several nitrogen-based organic catalysts for the depolymerization of poly(ethylene terephthalate) (PET), in which a few cyclic amidines work more effectively than a potent, bifunctional guanidine-based catalyst 1,5,7-triazabicyclo-[4,4,0]-dec- 5-ene (TBD) in the presence of short chain diols that play a role in activation of carbonyl groups through hydrogen bonding. Further studies prove that the catalytic efficiency at the above specific conditions depends only on the extent of activation of a hydroxyl group rather than simply the pKa of the bases. For glycolysis with excess short-chain alkanediols, 1,8-diazabicyclo[5.4. 0]undec-7-ene is the best catalyst. In contrast, TBD shows outstanding catalytic activity in depolymerizations of PET with mono-alcohols and longer-chain diols. Copyright © 2013 Wiley Periodicals, Inc.
Shiyi Chen, Daniel Martínez, et al.
Physics of Fluids
J.H. Kaufman, Owen R. Melroy, et al.
Synthetic Metals
Douglass S. Kalika, David W. Giles, et al.
Journal of Rheology
M. Hargrove, S.W. Crowder, et al.
IEDM 1998