An efficient synthesis of [1,1]ferrocenophane via 1,1′-bis(6-fulvenyl)ferrocene

U. Mueller-Westerhoff; A. Nazzal; W. Prössdorf

doi:10.1016/S0022-328X(00)82445-6

Journal of Organometallic Chemistry

Paper

10 Feb 1981

An efficient synthesis of [1,1]ferrocenophane via 1,1′-bis(6-fulvenyl)ferrocene

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Abstract

[1,1]Ferrocenophane can be prepared by reduction of 1,1′-bis(6-fulvenyl)ferrocene with complex borohydrides to give the dianion of 1,1′-bis(cyclopentadienylmethyl)ferrocene. Reaction of this dianion with ferrous chloride produces the ferrocenophane in good yield. © 1981.

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